Aminomatacil → HCID 21409297, compound

HRID 2072434Notes

Reaction equation

HRID 2072434 reaction equation
[CH3:1][NH:2][C:3](=[O:13])[O:4][C:5]1[CH:10]=[CH:9][C:8]([NH2:11])=[C:7]([CH3:12])[CH:6]=1.[Cl:14][CH2:15][S:16](Cl)(=[O:18])=[O:17]>>[CH3:1][NH:2][C:3](=[O:13])[O:4][C:5]1[CH:10]=[CH:9][C:8]([NH:11][S:16]([CH2:15][Cl:14])(=[O:18])=[O:17])=[C:7]([CH3:12])[CH:6]=1

Participants

3

Reactant 2

HCID 25072AminomatacilHCID 77054(Chloromethyl)sulfonyl chloride

Product 1

HCID 21409297HCID 21409297, compound

Procedure

According to the procedure of Example 2, 3-methyl-4-aminophenyl N-methylcarbamate (1.8g., 0.01 mole) was reacted with chloromethanesulfonyl chloride (1.63g., 0.011 mole). The product, recrystallized from ethanol/water, was an orange-red solid (m.p. 136.5°-38.5° C.).

Workup

  1. customThe product, recrystallized from ethanol/water

Sources & evidence

ORD record
ord-16d3d0d1feb34a1f88c207ae9ecf0da9
Source dataset
uspto-grants-1977_09
Patent number
US04051254

Reaction notes

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