2,6-Octadiene, 1-bromo-3,7-dimethyl-, (2E)- → HCID 53913159, compound

HRID 2072522Notes

Reaction equation

HRID 2072522 reaction equation
[CH2:1]([O:4][C:5](=[O:17])[C:6]1[CH:16]=[C:13]([O:14][CH3:15])[C:11]([OH:12])=[C:8]([O:9][CH3:10])[CH:7]=1)[C:2]#[CH:3].[CH2:18](Br)/[CH:19]=[C:20](/[CH2:22][CH2:23][CH:24]=[C:25]([CH3:27])[CH3:26])\[CH3:21]>>[CH2:1]([O:4][C:5](=[O:17])[C:6]1[CH:16]=[C:13]([O:14][CH3:15])[C:11]([O:12][CH2:18][CH:19]=[C:20]([CH3:21])[CH2:22][CH2:23][CH:24]=[C:25]([CH3:27])[CH3:26])=[C:8]([O:9][CH3:10])[CH:7]=1)[C:2]#[CH:3]

Participants

3

Reactant 2

HCID 53658672,6-Octadiene, 1-bromo-3,7-dimethyl-, (2E)-HCID 53977784HCID 53977784, compound

Product 1

HCID 53913159HCID 53913159, compound

Procedure

By utilizing the procedure of Example 1 by reacting syringic acid propargyl ester with geranyl bromide, there is obtained 4-[(3,7-dimethyl-2,6-octadienyl)oxy]-3,5-dimethoxy benzoic acid propargyl ester; nD21 = 1.5320

Sources & evidence

ORD record
ord-afdab73508ea44c79c097926242da117
Source dataset
uspto-grants-1977_09
Patent number
US04051319

Reaction notes

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