HuagongsheHuagongshe Chemistry Print Report · For research reference only
Butyryl chloride → 5-(4'-Pentylbiphenyl-4-yl)-2-propylpyridine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Butyryl chloride | HCID 8855 | — |
| Reactant | 1-Hexen-3-one | HCID 15395 | — |
| Reactant | 1,4-Pentadien-3-one | HCID 543199 | — |
| Reactant | 1-Piperidino-2-(4'-pentylbiphenyl-4-yl)ethene | HCID 54457147 | — |
| Product | 5-(4'-Pentylbiphenyl-4-yl)-2-propylpyridine | HCID 19859150 | — |
Reaction Steps
Example 11 is repeated by reacting hex-1-en-3-one (preparable starting from butanoyl chloride analogously to the vinyl ketone in Example 11) and 1-piperidino-2-(4'-pentylbiphenyl-4-yl)ethene (preparable analogously to the preparation of the enamine in Example 11) to give 5-(4'-pentylbiphenyl-4-yl)-2-propylpyridine having SE 178° SB 211° SA 222° I.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04913837 |
| Source dataset | uspto-grants-1990_04 |
| ORD ID | ord-819764159ce84ba18c8ad3c4d4e277cb |
| Source note | uspto-grants-1990_04 |