HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → 4'-(12-Bromododecyloxy)biphenyl-4-carboxylic acid ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 1,12-Dibromododecane | HCID 18766 | — |
| Reactant | Ethyl 4'-hydroxy-4-biphenylcarboxylate | HCID 4049156 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 4'-(12-Bromododecyloxy)biphenyl-4-carboxylic acid ethyl ester | HCID 53908401 | 67% |
Reaction Steps
An acetone solution of 90 m moles (21.8 g) of the above 4'-hydroxybiphenyl-4-carboxylic acid ethyl ester, 0.15 mole (49.2 g) of 1,12-dibromododecane, and 0.4 mole (55.3 g) of potassium carbonate was refluxed for four hours. The reaction solution was filtered. The filtrate was concentrated, and then purified by column chromatography, to obtain 29.5 g of 4'-(12-bromododecyloxy)biphenyl-4-carboxylic acid ethyl ester [m.p. 88.6°-90.5° C⟧ (yield: 67%)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04913839 |
| Source dataset | uspto-grants-1990_04 |
| ORD ID | ord-6cd3f833963a41e8a6bc92a9831a9762 |
| Source note | uspto-grants-1990_04 |