Sodium Azide → HCID 15531182, compound

HRID 2072660Notes

Reaction equation

HRID 2072660 reaction equation
[CH:1]1[CH:6]=[CH:5][C:4]([O:7][C:8](Cl)=[S:9])=[CH:3][CH:2]=1.[N-:11]=[N+:12]=[N-:13].[Na+]>CC(C)=O.O>[O:7]([C:8]1[S:9][N:13]=[N:12][N:11]=1)[C:4]1[CH:5]=[CH:6][CH:1]=[CH:2][CH:3]=1

Participants

5

Reactant 2

HCID 33557Sodium AzideHCID 70498Phenyl thioxochloroformate2×

Product 1

HCID 15531182HCID 15531182, compound

Reagents, catalysts & solvents 2

HCID 180AcetoneSolvent2×HCID 962WaterSolvent2×

Procedure

Phenyl chlorothionoformate (3.44 grams, 0.02 mole) was dissolved in 5 ml of dry acetone. Sodium azide (1.4 grams, 0.22 mole) was dissolved in 12 ml of deionized water with 8 ml of acetone and slowly added to the phenyl chlorothionoformate solution over a 5 minute period. The reaction was kept at 5° C. in an ice bath and stirred an additional 45 minutes before adding 12 ml of water. The solution was filtered to collect the product; m.p. 35°-36° C.

Workup

  1. customThe reaction was kept at 5° C. in an ice bath
  2. filtrationThe solution was filtered
  3. customto collect the product

Sources & evidence

ORD record
ord-f1536be94bfc4cf4a76f37f9e2de0f71
Source dataset
uspto-grants-1990_04
Patent number
US04914015

Reaction notes

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