Ethylene Glycol → 1,1'-[Ethane-1,2-diylbis(oxy)]bis(4-nitrobenzene)

HRID 2072859Notes

Reaction equation

HRID 2072859 reaction equation
[CH2:1]([OH:4])[CH2:2][OH:3].[N+:5]([C:8]1[CH:13]=[CH:12][C:11](Cl)=[CH:10][CH:9]=1)([O-:7])=[O:6].[OH-:15].[Na+]>CS(C)=O>[N+:5]([C:8]1[CH:13]=[CH:12][C:11]([O:3][CH2:2][CH2:1][O:4][C:11]2[CH:12]=[CH:13][C:8]([N+:5]([O-:6])=[O:15])=[CH:9][CH:10]=2)=[CH:10][CH:9]=1)([O-:7])=[O:6]

Participants

5

Reactant 3

HCID 174Ethylene GlycolHCID 74741-Chloro-4-nitrobenzeneHCID 14798Sodium Hydroxide

Product 1

HCID 2706471,1'-[Ethane-1,2-diylbis(oxy)]bis(4-nitrobenzene)

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

62 g (1 mol) ethylene glycol, 346.5 g (2.2 mols) 4-nitrochlorobenzene and 140 g powdered sodium hydroxide were reacted following the procedure described in Example 1 in 600 ml DMSO.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-528ca1992b0e4142a32ad5313d0529ae
Source dataset
uspto-grants-1990_04
Patent number
US04914238

Reaction notes

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