1-Chloro-4-nitrobenzene → 1,1'-[Ethane-1,2-diylbis(oxy)]bis(4-nitrobenzene)

HRID 2072860Notes

Reaction equation

HRID 2072860 reaction equation
[OH:1][CH2:2][CH2:3][O:4][C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[CH:7][CH:6]=1.[N+:14]([C:17]1[CH:22]=[CH:21][C:20](Cl)=[CH:19][CH:18]=1)([O-:16])=[O:15].[OH-].[Na+]>CS(C)=O>[N+:11]([C:8]1[CH:7]=[CH:6][C:5]([O:4][CH2:3][CH2:2][O:1][C:20]2[CH:21]=[CH:22][C:17]([N+:14]([O-:16])=[O:15])=[CH:18][CH:19]=2)=[CH:10][CH:9]=1)([O-:13])=[O:12]

Participants

5

Reactant 3

HCID 74741-Chloro-4-nitrobenzeneHCID 14798Sodium HydroxideHCID 853812-(4-Nitrophenoxy)ethanol

Product 1

HCID 2706471,1'-[Ethane-1,2-diylbis(oxy)]bis(4-nitrobenzene)

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

183 g (1 mol) 1-(2-hydroxyethoxy)-4-nitrobenzene, 173.3 g (1.1 mols) 4-nitrochlorobenzene and 70 g powdered sodium hydroxide were reacted following the procedure described in Example 1 in 600 ml DMSO.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-725ff21339754c5a8235f2b03ec92d11
Source dataset
uspto-grants-1990_04
Patent number
US04914238

Reaction notes

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