HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Carbonate → 4-benzoyl-2-nitro-N-(4'-chloro-3'-sulfamoylbenzoyl)phenylhydrazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | 3-(Aminosulfonyl)-4-chlorobenzoyl chloride | HCID 3017979 | — |
| Reactant | 4-Benzoyl-2-nitrophenylhydrazine | HCID 19858128 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | 4-benzoyl-2-nitro-N-(4'-chloro-3'-sulfamoylbenzoyl)phenylhydrazine | HCID 86743847 | 61% |
Reaction Steps
By using the process of Example 1(B), 28 g of 4-benzoyl-2-nitrophenylhydrazine, 272 ml of dioxane, 5.8 g of anhydrous sodium carbonate dissolved in 110 ml of water and 27.6 g of 4-chloro-3-sulfamoylbenzoyl chloride dissolved in 217 ml of dioxane were used as starting materials to yield 29.1 g (61%) of 4-benzoyl-2-nitro-N-(4'-chloro-3'-sulfamoylbenzoyl)phenylhydrazine, m.p.: 148° C. after recrystallization from methanol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04916149 |
| Source dataset | uspto-grants-1990_04 |
| ORD ID | ord-fd3d34ae03184bbcb2357cd09c7cbdd9 |
| Source note | uspto-grants-1990_04 |