N,N-Dimethylbenzylamine → HCID 54190960, compound

Participants

Reaction Conditions

Reaction Steps

2.13 g (11.1 mmols) of 4-chloroformylcinnamonitrile, 2.24 g (11.1 mmols) of 4-bromostyrene, 1.51 g (11.1 mmols) of N-benzyldimethylamine and 0.0246 g (0.11 mmol) of palladium acetate are added under argon to 30 ml of p-xylene, and the reaction mixture is stirred at 130° C. for 1.5 hours. The crude product which has been precipitated is filtered off at room temperature and is recrystallised from methanol and then from carbon tetrachloride. 0.38 g (11% of theory) of 4-bromostilbene-4'-acrylonitrile are obtained; melting point 258° C.

Provenance & Evidence