Aluminum(III) Chloride → HCID 16792220, compound

HRID 2073740Notes

Reaction equation

HRID 2073740 reaction equation
[N:1]([CH2:4][CH:5]([N:14]1[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]1)[C:6]1[CH:11]=[CH:10][C:9]([Cl:12])=[CH:8][C:7]=1[Cl:13])=[N+]=[N-].[H-].[Al+3].[Li+].[H-].[H-].[H-].[Cl-].[Al+3].[Cl-].[Cl-]>>[Cl:13][C:7]1[CH:8]=[C:9]([Cl:12])[CH:10]=[CH:11][C:6]=1[CH:5]([N:14]1[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]1)[CH2:4][NH2:1]

Participants

4

Reactant 3

HCID 6451240Aluminum(III) ChlorideHCID 19855906HCID 19855906, compoundHCID 21226445Aluminium lithium hydride

Product 1

HCID 16792220HCID 16792220, compound

Procedure

In a manner similar to Preparation 5 react 1-[2-azido-1-(2,4-dichlorophenyl)ethyl]piperidine with lithium aluminum hydride and aluminum chloride to obtain the title compound.

Workup

  1. customIn a manner similar to Preparation 5

Sources & evidence

ORD record
ord-e11e0b43fe10437da9e5f983f412b88f
Source dataset
uspto-grants-1990_04
Patent number
US04920116

Reaction notes

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