HCID 14995002, compound → HCID 14800666, compound

HRID 2073871Notes

Reaction equation

HRID 2073871 reaction equation
[OH:1][C:2]1[CH:19]=[CH:18][C:5]([C:6]([C:8]2[CH:9]=[C:10]([CH:15]=[CH:16][CH:17]=2)[C:11]([O:13][CH3:14])=[O:12])=O)=[CH:4][CH:3]=1.[H][H]>C(O)C.[Pd]>[OH:1][C:2]1[CH:3]=[CH:4][C:5]([CH2:6][C:8]2[CH:9]=[C:10]([CH:15]=[CH:16][CH:17]=2)[C:11]([O:13][CH3:14])=[O:12])=[CH:18][CH:19]=1

Participants

5

Reactant 2

HCID 14995002HCID 14995002, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 14800666HCID 14800666, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

Methyl 3-(4-hydroxybenzoyl)benzoate (0.1 mol) in absolute ethanol (500 ml) is shaken under 50 psi of hydrogen in the presence of 10% palladium on carbon (2 g). After consumption of the starting material the suspension is filtered and evaporated to give methyl 3-(4-hydroxybenzyl)benzoate.

Workup

  1. customAfter consumption of the starting material the suspension
  2. filtrationis filtered
  3. customevaporated

Sources & evidence

ORD record
ord-6b49db0224c14d9bb70ba8f386ca18ca
Source dataset
uspto-grants-1990_04
Patent number
US04920133

Reaction notes

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