tert-Butoxy bis(dimethylamino)methane → HCID 67096103, 화합물

HRID 2076055노트

반응식

HRID 2076055 반응식
[F:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]2[CH2:13][CH2:12][CH2:11][CH2:10][C:9]2=[O:14])=[CH:4][CH:3]=1.C(O[CH:20](N(C)C)[N:21]([CH3:23])[CH3:22])(C)(C)C>>[CH3:20][N:21]([CH3:23])[CH:22]=[C:10]1[C:9](=[O:14])[CH:8]([C:5]2[CH:4]=[CH:3][C:2]([F:1])=[CH:7][CH:6]=2)[CH2:13][CH2:12][CH2:11]1

참가 물질

3

반응물 2

HCID 79885tert-Butoxy bis(dimethylamino)methaneHCID 130895402-(4-Fluorophenyl)cyclohexan-1-one

생성물 1

HCID 67096103HCID 67096103, 화합물

실험 절차

2-(4-Fluoro-phenyl)-cyclohexanone (102 mg, 0.53 mmol) was reacted with tert.-butoxy-bis-(dimethylamino)-methane using in analogous manner the procedure described in example 45a) to give crude title compound (143 mg) as a red oil which was used directly in the next step. MS ISP (m/e): 248.1 [(M+H)+].

출처 및 근거

ORD 기록
ord-e8ca85a885004543b72c741b176906c0
출처 데이터셋
uspto-grants-2011_04
특허 번호
US07923450B2

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