HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol → HCID 86617432, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol | HCID 2734624 | — |
| Reactant | HCID 86617433 | HCID 86617433 | — |
| Product | HCID 86617432 | HCID 86617432 | 77% |
Reaction Steps
According to a method similar to Example (26-3) and Example (68), from methyl {4-bromo-2-[(dimethylamino)carbonyl]phenyl}acetate (102 mg, 0.340 mmol) and 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol (90 mg, 0.408 mol), methyl {3-[(dimethylamino)carbonyl]-4′-hydroxy-1,1′-biphenyl-4-yl}acetate was obtained (82 mg, two-step total yield: 77%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07923573B2 |
| Source dataset | uspto-grants-2011_04 |
| ORD ID | ord-39b21875f1a641938430d493c7cdc077 |
| Source note | uspto-grants-2011_04 |