2,5-Dimethoxyphenol → HCID 86638524, compound

HRID 2079450Notes

Reaction equation

HRID 2079450 reaction equation
F[C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[C:4]([N+:11]([O-:13])=[O:12])[C:3]=1[CH3:14].[CH3:15][O:16][C:17]1[CH:22]=[CH:21][C:20]([O:23][CH3:24])=[CH:19][C:18]=1[OH:25]>>[N+:11]([C:4]1[C:3]([CH3:14])=[C:2]([C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=1)[O:25][C:18]1[CH:19]=[C:20]([O:23][CH3:24])[CH:21]=[CH:22][C:17]=1[O:16][CH3:15])([O-:13])=[O:12]

Participants

3

Reactant 2

HCID 53144982,5-DimethoxyphenolHCID 86638525HCID 86638525, compound

Product 1

HCID 86638524HCID 86638524, compound

Procedure

The process was carried out as indicated in point 5.4. above, using 0.366 g (1.83 mmol) of the 2-fluoro-3,6-dinitrotoluene prepared in point 7.4. above and 0.282 g (1.83 mmol) of 2,5-dimethoxyphenol prepared in point 7.5. above. The title product was isolated in the form of a yellow solid, using a 70:30 mixture of light mineral spirit (60-80° C.):diethyl ether as eluent (0.400 g, 65.5%).

Workup

  1. customprepared in point 7.4

Sources & evidence

ORD record
ord-28599cd2a4b1467496c6c6262f8aadbe
Source dataset
uspto-grants-2011_04
Patent number
US07932050B2

Reaction notes

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