Diethyl Ether → HCID 136367088, compound

HRID 2080653Notes

Reaction equation

HRID 2080653 reaction equation
IC1[C:3]([O:22]C)=[CH:4][C:5]([O:20]C)=[C:6]([C:8]2[N:12]([C:13]3[CH:18]=[CH:17][CH:16]=[C:15]([CH3:19])[CH:14]=3)[N:11]=[CH:10][CH:9]=2)[CH:7]=1.[CH3:24][C:25]([CH2:27][CH3:28])=[CH2:26].[CH3:29]COCC>>[CH3:26][CH:25]([CH2:24][CH3:29])[CH2:27][C:28]1[C:3]([OH:22])=[CH:4][C:5]([OH:20])=[C:6]([C:8]2[N:12]([C:13]3[CH:18]=[CH:17][CH:16]=[C:15]([CH3:19])[CH:14]=3)[N:11]=[CH:10][CH:9]=2)[CH:7]=1

Participants

4

Reactant 3

HCID 3283Diethyl EtherHCID 112402-Methyl-1-buteneHCID 67100392HCID 67100392, compound

Product 1

HCID 136367088HCID 136367088, compound

Procedure

12.4 Analogous reaction of 5-[5-iodo-2,4-dimethoxyphenyl]1-(3-methylphenyl)-1H-pyrazole with 2-methyl-1-butene, hydrogenation and ether cleavage gives the compound 5-{5-(2-methylbutyl)-2,4-dihydroxyphenyl}-1-(3-methylphenyl)-1H-pyrazole.

Sources & evidence

ORD record
ord-005b75a433bd471fb49a3c036eafb39d
Source dataset
uspto-grants-2011_04
Patent number
US07932401B2

Reaction notes

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