Chlorine → Sulfur, (3-chloro-4-hydroxyphenyl)pentafluoro-, (OC-6-21)-
Reaction equation
[F:1][S:2]([F:13])([F:12])([F:11])([F:10])[C:3]1[CH:8]=[CH:7][C:6]([OH:9])=[CH:5][CH:4]=1.[Cl:14]Cl>C(O)(=O)C>[Cl:14][C:7]1[CH:8]=[C:3]([S:2]([F:10])([F:11])([F:12])([F:13])[F:1])[CH:4]=[CH:5][C:6]=1[OH:9]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Conditions
- Temperature
- 30 °C
Procedure
5.00 g of 4-pentafluorosulfanylphenol (prepared in example 11a) were dissolved in 100 ml of acetic acid and a chlorine gas stream was passed through at 0° C. for 10 minutes. This warmed the solution to 30° C. which was subsequently stirred at RT for a further 90 minutes. Argon was used to drive the chlorine out of the solution and the solvent was subsequently removed under reduced pressure. 5.50 g of a pale yellow oil were obtained.
Workup
- customthe solvent was subsequently removed under reduced pressure
Sources & evidence
- ORD record
- ord-3381cb3c4fea42d6b3010e8e233a6eb3
- Source dataset
- uspto-grants-2011_04
- Patent number
- US07932416B2
Reaction notes
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