HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Chloroaniline → Benzenediazonium, 4-chloro-, chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Chloroaniline | HCID 7812 | — |
| Reactant | Sodium Nitrite | HCID 23668193 | — |
| Solvent | Hydrochloric Acid | HCID 313 | — |
| Solvent | Water | HCID 962 | — |
| Product | Benzenediazonium, 4-chloro-, chloride | HCID 11819533 | — |
Reaction Steps
To a suspension of 4-chloroaniline (21.14 g, 0.166 mol) in water (156 ml) and 12N HCl (46 ml) at 0° was added sodium nitrite (12.62 g, 0.182 mol) in water (156 ml) over 20 minutes keeping the reaction temperature below 10°. The solution of 4-chlorobenzenediazonium chloride was filtered, kept at 0° for 30 minutes and then used in the next step.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05185459 |
| Source dataset | uspto-grants-1993_02 |
| ORD ID | ord-1f10dbf4834749f4b343fea5978731d7 |
| Source note | uspto-grants-1993_02 |