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HRID2081899

反应详情

EQUATION

反应方程式

HRID 2081899 的结构方程式

REACTANTS

反应物

2
结构：COS(=O)(=O)[O-]
HCID4694097

Methyl sulfate

CH3O4S-

2 次

结构：Cc1ccc(S(=O)(=O)Nc2cccc([N+](=O)[O-])c2N)cc1
HCID14147502

未命名化合物

PRODUCTS

生成物

1
结构：Cc1ccc(S(=O)(=O)N(C)c2cccc([N+](=O)[O-])c2N)cc1
HCID19778848

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：[Na+].[OH-]
溶剂HCID14798

Sodium Hydroxide

HNaO

2 次

PROCEDURE

实验过程

0.093 mol (28.5 g) of 2-amino-3-nitro-N-tosylaniline is dissolved in 112 ml of normal sodium hydroxide solution at 30° C. 0.122 mol (15.45 g) of methyl sulphate is added gradually, in the course of 1 hour 30 minutes, whilst stirring. The temperature remains between 35° and 40° C. Towards the end of the addition of the methyl sulphate, 3 ml of 10N sodium hydroxide solution are gradually added simultaneously in order to keep the pH alkaline.

WORKUP

后处理

  1. customremains between 35° and 40° C
  2. additionare gradually added simultaneously in order