Aniline → HCID 86744679, compound

HRID 2081934Notes

Reaction equation

HRID 2081934 reaction equation
[S:1]([C:5]1[CH:11]=[CH:10][C:8]([CH3:9])=[CH:7][CH:6]=1)([O-:4])(=[O:3])=[O:2].[NH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[NH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.[S:1]([C:5]1[CH:11]=[CH:10][C:8]([CH3:9])=[CH:7][CH:6]=1)([O-:4])(=[O:3])=[O:2]

Participants

3

Reactant 2

HCID 6115Aniline3×HCID 85570p-Toluenesulfonate3×

Product 1

HCID 86744679HCID 86744679, compound

Procedure

Usable polymer films of polyaniline/tosylate are formed when the concentration range is limited to between about 0.8 and 1M for tosylate and between about 0.05 and 0.2M for aniline. The results of the half-cell battery test are summarized above in Table 4. No substantial difference in terms of the half-cell performance was observed when the concentration of aniline is increased from between about 0.1M and 0.2M or the concentration of tosylate is decreased from between about 1M to 0.8M. However, a low concentration of aniline, i.e. 0.05M, gives a poorer performance (PAN 96). A preferred concentration range is: aniline: 0.1M to 0.2M; tosylate: 0.8M to 1M.

Workup

  1. customThe results of the half-cell battery test
  2. temperatureis increased from between about 0.1M and 0.2M
  3. concentrationHowever, a low concentration of aniline, i.e. 0.05M
  4. customgives a poorer performance (PAN 96)

Sources & evidence

ORD record
ord-4b2f165c0ebb4c2497954cb874ea19e2
Source dataset
uspto-grants-1993_02
Patent number
US05187034

Reaction notes

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