1-Ethenyl-4-nitrobenzene → 1-Ethenyl-4-nitrobenzene

HRID 2081948Notes

Reaction equation

HRID 2081948 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([CH:10]=[CH2:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].Br[CH2:13][CH2:14][C:15]1[CH:20]=[CH:19][C:18]([N+:21]([O-:23])=[O:22])=[CH:17][CH:16]=1>>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([CH2:10][CH:11]=[O:22])=[CH:6][CH:5]=1)([O-:3])=[O:2].[N+:21]([C:18]1[CH:19]=[CH:20][C:15]([CH:14]=[CH2:13])=[CH:16][CH:17]=1)([O-:23])=[O:22]

Participants

4

Reactant 2

HCID 74811-Ethenyl-4-nitrobenzeneHCID 792664-Nitrophenethyl bromide

Product 2

HCID 74811-Ethenyl-4-nitrobenzeneHCID 11744988(4-Nitrophenyl)acetaldehyde

Procedure

p-Nitrophenylacetaldehyde was prepared by the method described in Lethbridge et al., J. Chem. Soc. Perkin I, 35 1973) from p-nitrophenylethylene. The p-nitrophenylethylene was prepared by the method described in Strassburg et al., J. Am. Chem. Soc. 69:2142 (1947) from 1-bromo-2-(p-nitrophenyl)ethane commercially obtainable from Aldrich Chemical Co., Milwaukee, Wis.).

Sources & evidence

ORD record
ord-f684d861313c4ac480370e4c7a598173
Source dataset
uspto-grants-1993_02
Patent number
US05187086

Reaction notes

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