HCID 14307133, compound → HCID 14307135, compound

HRID 2082476Notes

Reaction equation

HRID 2082476 reaction equation
CC1C2C=CC(OC3C=CC([N+]([O-])=O)=CN=3)=CC=2OC1.[CH3:21][CH:22]1[C:26]2[CH:27]=[CH:28][C:29]([O:31][C:32]3[CH:37]=[CH:36][C:35]([N+:38]([O-])=O)=[CH:34][CH:33]=3)=[CH:30][C:25]=2[O:24][CH2:23]1>>[CH3:21][CH:22]1[C:26]2[CH:27]=[CH:28][C:29]([O:31][C:32]3[CH:37]=[CH:36][C:35]([NH2:38])=[CH:34][CH:33]=3)=[CH:30][C:25]=2[O:24][CH2:23]1

Participants

3

Reactant 2

HCID 14307133HCID 14307133, compoundHCID 14307134HCID 14307134, compound

Product 1

HCID 14307135HCID 14307135, compoundYield 98%

Procedure

The procedure of Example 1 was repeated except that the 2-(3-methyl-2,3-dihydro-6-benzofuryloxy)-5-nitropyridine was replaced by 4-(3-methyl-2,3-dihydro-6-benzofuryloxy)nitrobenzene. The reaction mixture was worked up in the same manner as in Example 1, obtaining the end product in the form of brown liquid (yield 98%).

Sources & evidence

ORD record
ord-64e47f62b8a44c568cb92ce2401a3fe8
Source dataset
uspto-grants-1993_02
Patent number
US05189183

Reaction notes

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