HuagongsheHuagongshe Chemistry Print Report · For research reference only
Iodine → 1,1'-(Diazomethylene)bis(benzene)
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Iodine | HCID 807 | — |
| Reactant | Peracetic Acid | HCID 6585 | — |
| Reactant | Diphenylmethylidenehydrazine | HCID 79304 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 1,1'-(Diazomethylene)bis(benzene) | HCID 61230 | — |
Reaction Steps
To benzophenone hydrazone (4.9 g, 0.025 moles) in dimethylformamide (25 ml) containing iodine (1 ml, 1% w/v solution) and excess Dowex 1 × 2 quaternary ammonium hydroxide resin saturated with dimethyl formamide was added peracetic acid solution (5.7 ml, 1.27 × 0.025 m. moles) at 15° over 60 minutes.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04083837 |
| Source dataset | uspto-grants-1978_04 |
| ORD ID | ord-d65c50f7aae244e8a3fccd417373dd2c |
| Source note | uspto-grants-1978_04 |