HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-{[(3-Methoxypyridin-2-yl)methyl]sulfanyl}ethan-1-amine → HCID 70509255, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-{[(3-Methoxypyridin-2-yl)methyl]sulfanyl}ethan-1-amine | HCID 12951535 | — |
| Reactant | 1-Nitro2-methylthio-2-methylsulphinylethylene | HCID 54487094 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 70509255 | HCID 70509255 | 56.9% |
Reaction Steps
A solution of 2-[2-aminoethylthiomethyl]-3-methoxypyridine (2.1 g) in methanol (33 ml) was added over 25 minutes to a stirred solution of 1-methylthio-1-methylsulphinyl-2-nitroethylene (2.1 g) in methanol (75 ml) at 30°. After standing for an hour the solution was concentrated to give a yellow-brown oil which was crystallised from ethanol/ether to yield 1-methylthio-1-[2-((3-methoxy-2-pyridyl)methylthio)ethylamino]-2-nitroethylene (1.9 g), m.p. 87.5° - 88.5°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04083983 |
| Source dataset | uspto-grants-1978_04 |
| ORD ID | ord-ecc1e98649ee4bb687c092f44ef9e375 |
| Source note | uspto-grants-1978_04 |