HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide dimethyl acetal → 1,4,8-Triazatricyclo[6.3.1.04,12]dodecane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide dimethyl acetal | HCID 78373 | — |
| Reactant | 1,4,8-Triazacycloundecane | HCID 398742 | — |
| Product | 1,4,8-Triazatricyclo[6.3.1.04,12]dodecane | HCID 12641658 | 81.8% |
Reaction Steps
In a manner similar to that of Example 1 (C), 5.28 g (33.6 mmol) of 1,4,8-triazacycloundecane and 4.00 g of dimethylformamide dimethyl acetal were reacted to give 4.59 g of 1,4,8-triazatricyclo[6.3.1.04,12 ]dodecane as a clear, colorless liquid, bp 80°-82° (three fractions) (1.2 mm), nD24 = 1.5182. A fraction boiling at 82° was analyzed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04085106 |
| Source dataset | uspto-grants-1978_04 |
| ORD ID | ord-5603751896474c1882acb948c7275418 |
| Source note | uspto-grants-1978_04 |