HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosgene → 1,3-Dibutyl-1,3,5-triazinane-2,4,6-trione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosgene | HCID 6371 | — |
| Reactant | Dibutylurea | HCID 74523 | — |
| Reactant | Potassium cyanate | HCID 11378442 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 1,3-Dibutyl-1,3,5-triazinane-2,4,6-trione | HCID 21820787 | 38% |
Reaction Steps
A benzene solution (50 ml) of 5,3-dibutyl allophanoyl chloride (0.1 mole) was prepared by reaction of phosgene with 1,3-dibutyl urea by the method of Example 2. This material was reacted with 16.0 g (0.2 mole) of potassium cyanate as described above. After work-up, 9.3 g (38% yield) of dibutyl isocyanuric acid was obtained; m.p. 86°-88° C. IR and nmr analysis was consistent with the assigned structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04085268 |
| Source dataset | uspto-grants-1978_04 |
| ORD ID | ord-41f14472460441a7a7dddddd6240d4bf |
| Source note | uspto-grants-1978_04 |