HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chloroform → HCID 14200217, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chloroform | HCID 6212 | — |
| Reactant | Diazomethane | HCID 9550 | — |
| Reactant | HCID 12670843 | HCID 12670843 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | HCID 14200217 | HCID 14200217 | — |
Reaction Steps
2(R),6(R),10-trimethylundecanoic acid (270 mg., [α]D25 -8.64°) was dissolved in ether and treated with an excess of etheral solution of diazomethane at 23° C. for 2.0 hour. The crude product was subjected to evaporative distillation at 98°-101°/0.15 mm Hg to give 247 mg. of 2(R), 6(R),10-trimethylundecanoic acid methyl ester as a colorless oil, [α]D25 -11.30° (c1.1065, CHCl3).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04086249 |
| Source dataset | uspto-grants-1978_04 |
| ORD ID | ord-4a0e96ade02049e8b7f50083a7200b7b |
| Source note | uspto-grants-1978_04 |