HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2083855Generated: November 1, 2026
Triphenylphosphine → HCID 15219974, compound
https://huagongshe.com/reaction/2083855
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | Bromine | HCID 24408 | — |
| Reactant | HCID 178455721 | HCID 178455721 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | HCID 15219974 | HCID 15219974 | — |
Reaction Steps
102 ml of bromine are added dropwise over the course of 2 hours at 5-15° C. to 536 g of triphenylphosphine in 2000 ml of acetonitrile, the mixture is subsequently stirred at 5° C. for 1 hour, 422 g of 4-(trans-4-ethyl-cyclohexyl)cyclohexanol are added, and the mixture is stirred at RT for 24 hours. Conventional work-up gives 4′-bromo-4-ethylbicyclohexane, GC 94.7%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06716491B2 |
|---|
| Source dataset | uspto-grants-2004_04 |
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| ORD ID | ord-432ff21c4ec44296b24103780a81f382 |
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| Source note | uspto-grants-2004_04 |
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