Geniosil GF 92 → Ethylene butyl acrylate

HRID 2084568Notes

Reaction equation

HRID 2084568 reaction equation
C=C.[CH2:3]([O:7][C:8](=[O:11])[CH:9]=[CH2:10])[CH2:4][CH2:5][CH3:6].C(OCC1OC1)(=O)C(C)=C.C1(NCCC[Si](OC)(OC)OC)CCCCC1.N[SiH3]>>[CH2:3]=[CH2:4].[C:8]([O:7][CH2:3][CH2:4][CH2:5][CH3:6])(=[O:11])[CH:9]=[CH2:10]

Participants

4

Reactant 3

HCID 76477Geniosil GF 92HCID 6452341Ethylene n-butylacrylate glycidyl methacrylateHCID 14094712CID 14094712

Product 1

HCID 16212797Ethylene butyl acrylate

Procedure

45 g. of an ethylene/n-butylacrylate/glycidyl methacrylate containing 4 wt. % GMA and 30 weight percent nBA and having a melt index of 1000 was reacted with 3.3 g. of N-cyclohexylaminopropyl trimethoxysilane in a Brabender mixer at 160° C. for 10 min. Rotor speed was 100 rpm. This represents a stoichiometric balance of aminosilane to the glycidyl moiety. The MI of the grafted product was 1098. This is above that of the direct copolymer which suggests that little or no crosslinking occurred during the preparation of the grafted copolymer.

Workup

  1. customwas reacted with 3.3 g
  2. customoccurred during the preparation of the grafted copolymer

Sources & evidence

ORD record
ord-08ef2eed57884c7cbc8687e878770dfc
Source dataset
uspto-grants-2004_04
Patent number
US06716920B2

Reaction notes

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