2-Nitrobenzyl alcohol → HCID 22733953, compound

HRID 2084786Notes

Reaction equation

HRID 2084786 reaction equation
[C:1]([CH2:4][C:5]1[C:9]2[C:10]([C:16](=[O:26])[CH2:17][C:18]3[C:23]([Cl:24])=[CH:22][N:21]=[CH:20][C:19]=3[Cl:25])=[CH:11][CH:12]=[C:13]([O:14][CH3:15])[C:8]=2[O:7][CH:6]=1)([OH:3])=[O:2].[N+:27]([C:30]1[CH:37]=[CH:36][CH:35]=[CH:34][C:31]=1[CH2:32]O)([O-:29])=[O:28]>>[Cl:24][C:23]1[CH:22]=[N:21][CH:20]=[C:19]([Cl:25])[C:18]=1[CH2:17][C:16]([C:10]1[C:9]2[C:5]([CH2:4][C:1]([O:3][CH2:32][C:31]3[CH:34]=[CH:35][CH:36]=[CH:37][C:30]=3[N+:27]([O-:29])=[O:28])=[O:2])=[CH:6][O:7][C:8]=2[C:13]([O:14][CH3:15])=[CH:12][CH:11]=1)=[O:26]

Participants

3

Reactant 2

HCID 119232-Nitrobenzyl alcoholHCID 22733964HCID 22733964, compound

Product 1

HCID 22733953HCID 22733953, compoundYield 38%

Procedure

Substantially the same procedure as in Example 13 was repeated using Compound 151 (0.30 g) obtained in Example 151 and 2-nitrobenzyl alcohol (0.12 g) to give Compound 154 (0.15 g, 38%) as white crystals.

Sources & evidence

ORD record
ord-b70c5242fab343cc9e6eb302205c3f56
Source dataset
uspto-grants-2004_04
Patent number
US06716987B1

Reaction notes

Loading…