Succinimide → Monosodium Aspartate

HRID 2085478Notes

Reaction equation

HRID 2085478 reaction equation
[NH2:1][C@H:2]([C:7]([O-:9])=[O:8])[CH2:3][C:4]([OH:6])=[O:5].[Na+:10].C1(=O)[NH:15]C(=O)CC1>>[NH2:1][C@H:2]([C:7]([O-:9])=[O:8])[CH2:3][C:4]([OH:6])=[O:5].[Na+:10].[NH2:1][C@H:2]([C:7]([O-:9])=[O:8])[CH2:3][C:4]([OH:6])=[O:5].[NH4+:15]

Participants

4

Reactant 2

HCID 11439SuccinimideHCID 23672344Monosodium Aspartate

Product 2

HCID 23672344Monosodium AspartateHCID 24180699L-Aspartic acid, ammonium salt (1:1)

Procedure

FIG. 9. Infrared spectrum of the 2:1 copolymer of monosodium aspartate and succinimide, produced via thermal polymerization of monosodium aspartate and monoammonium aspartate at 200° C. for 3 hours. The amide peaks in the region of 1600 cm−1 became more prominent with increasing relative amounts of monosodium aspartate monomer. The imide peak at ˜1716 cm−1 tended to become accentuated with longer reaction times, as aspartic acid residues were driven more toward the succinimide form. Again, the carboxylate peak at ˜1400 cm−1 is prominent and the monomeric peaks in the fingerprint region (<1000 cm−1) are absent.

Sources & evidence

ORD record
ord-2b2065e067c14ae19ae83ebf6c5bb35f
Source dataset
uspto-grants-2004_04
Patent number
US06720405B2

Reaction notes

Loading…