Sodium ion → 10-bromo-2-hydroxy-5-(2-pyridylmethyl)-4H-pyrido[3,2,1-jk]carbazole-4-one

HRID 208581Notes

Reaction equation

HRID 208581 reaction equation
[B:28]([Br:29])([Br:30])[Br:31].[Br:1][c:2]1[cH:3][cH:4][c:5]2[n:6]3[c:7]4[c:8]([cH:9][c:10]([O:15][CH3:16])[cH:11][c:12]4[c:13]2[cH:14]1)[c:17](=[O:27])[c:18]([CH2:20][c:21]1[n:22][cH:23][cH:24][cH:25][cH:26]1)[cH:19]3.[CH2:38]([Cl:39])[Cl:40].[Na+:32].[Na+:33].[O-:34][C:35](=[O:36])[O-:37]>>[Br:1][c:2]1[cH:3][cH:4][c:5]2[n:6]3[c:7]4[c:8]([cH:9][c:10]([OH:15])[cH:11][c:12]4[c:13]2[cH:14]1)[c:17](=[O:27])[c:18]([CH2:20][c:21]1[n:22][cH:23][cH:24][cH:25][cH:26]1)[cH:19]3

Participants

6

Reactant 5

HCID 923Sodium ion2×HCID 6344DichloromethaneHCID 19660Carbonate IonHCID 25134Boron tribromideHCID 1936490010-bromo-2-methoxy-5-(2-pyridylmethyl)-4H-pyrido[3,2,1-jk]carbazole-4-one

Product 1

HCID 1936490510-bromo-2-hydroxy-5-(2-pyridylmethyl)-4H-pyrido[3,2,1-jk]carbazole-4-one

Sources & evidence

ORD record
ord-8ec7f0bf1bf74371b028fbab0fcba090
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

Loading…