HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trichloroacetonitrile → HCID 10962910, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trichloroacetonitrile | HCID 11011 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-D-glucopyranose | HCID 10928224 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 10962910 | HCID 10962910 | — |
Reaction Steps
To a solution of 36 (4.0 g, 6.98 mmol) and trichloroacetonitril (4.2 ml, 14.88 mmol) in CH2Cl2 (25 ml) 18 g of finely powdered dry K2CO3 are added. After stirring for 60 min at RT the mixture is filtered through Celite®. Chromatography (silica gel, 500 g, hexane/ethyl acetate=2:1) gives 37 (β-anomer).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06723831B2 |
| Source dataset | uspto-grants-2004_04 |
| ORD ID | ord-589e4b30473b479ea8dc14c097a49d3e |
| Source note | uspto-grants-2004_04 |