Tetrahydrofuran → HCID 131730563, compound

Participants

Reaction Steps

A flask equipped with a stirrer, reflux condenser, dropping funnel and thermometer was charged with 53.3 g (0.18 mol) of bistrimethylsilylaminopropyldimethylchlorosilane. To the flask, 160 mL (0.22 mol) of a tetrahydrofuran solution of 1.4M vinylmagnesium chloride was added dropwise over 2 hours at an internal temperature of 60-70° C. Stirring was continued for 4 hours at the temperature. A salt formed was removed by filtration. By subsequent distillation, 40.7 g of a fraction having a boiling point of 94° C./0.4 kPa was collected.

Provenance & Evidence