HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2090183Generated: October 30, 2026
1-(3-Allyl-2-hydroxyphenyl)ethanone → 1-{2-Hydroxy-3-[(1E)-prop-1-en-1-yl]phenyl}ethanone
https://huagongshe.com/reaction/2090183
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1-(3-Allyl-2-hydroxyphenyl)ethanone | HCID 13026916 | — |
| Catalyst | Bis(benzonitrile)palladium chloride | HCID 498840 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 1-{2-Hydroxy-3-[(1E)-prop-1-en-1-yl]phenyl}ethanone | HCID 11008454 | — |
Reaction Steps
40 g (227 mmol) of 1-(3-allyl-2-hydroxyphenyl)ethanone are dissolved in 120 ml of toluene, and 2.17 g (5.6 mmol) of bis(benzonitrile)dichloropalladium(II) are added. The reaction mixture is heated at 120° C. overnight. Cooling to room temperature is followed by filtration through kieselguhr, and the solvent is removed in vacuo. 20.9 g (95% of theory) of the title compound are obtained and are reacted without further purification in the next stage.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US08436180B2 |
|---|
| Source dataset | uspto-grants-2013_05 |
|---|
| ORD ID | ord-3bf1d832bfcf4008ba3035b0ba5e0ad0 |
|---|
| Source note | uspto-grants-2013_05 |
|---|
