HuagongsheHuagongshe Chemistry Print Report · For research reference only
5-Octanoyl-2,2-dimethyl-1,3-dioxane-4,6-dione → Decanoic acid, 3-oxo-, ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5-Octanoyl-2,2-dimethyl-1,3-dioxane-4,6-dione | HCID 356703 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | Decanoic acid, 3-oxo-, ethyl ester | HCID 83224 | 90% |
Reaction Steps
The resulting 5-octanoyl-2,2-dimethyl-1,3-dioxane-4,6-dione was allowed to reflux in ethanol for 2 hours, and then concentrated under reduced pressure. The resulting residue was purified using silica gel chromatography (developing solvent: n-hexane/ethyl acetate=8/2) to obtain ethyl 3-oxodecanoate shown by the formula below.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08436210B2 |
| Source dataset | uspto-grants-2013_05 |
| ORD ID | ord-bdc9956995c44e2fb99da03739adaad8 |
| Source note | uspto-grants-2013_05 |