HuagongsheHuagongshe Chemistry Print Report · For research reference only
(4E)-6-Fluoro-N-methoxy-3,4-dihydro-2H-1-benzopyran-4-imine → 6-fluoro-3,4-dihydro-2H-1-benzopyran-4-amine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (4E)-6-Fluoro-N-methoxy-3,4-dihydro-2H-1-benzopyran-4-imine | HCID 73696137 | — |
| Reactant | (4E)-N-Methoxy-6-methyl-3,4-dihydro-2H-1-benzopyran-4-imine | HCID 86605441 | — |
| Product | 6-fluoro-3,4-dihydro-2H-1-benzopyran-4-amine | HCID 16244413 | — |
Reaction Steps
The title compound was prepared using the procedure as described in Example 7B, substituting the product of Example 10A for the product of Example 7A. 1H NMR (300 MHz, CDCl3) δ 7.03 (dd, 1H, J=9.1 and 3.1 Hz), 6.85 (m, 1H), 6.74 (m, 1H), 4.15-4.29 (m, 2H), 4.02 (m, 1H), 2.10-2.20 (m, 1H), 1.79-1.89 (m, 1H). MS (DCI) m/e 168 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08440691B2 |
| Source dataset | uspto-grants-2013_05 |
| ORD ID | ord-d5ee96e26d534624a206416d42c5b9b6 |
| Source note | uspto-grants-2013_05 |