HuagongsheHuagongshe Chemistry Print Report · For research reference only
(4E)-N-Methoxy-6-methyl-3,4-dihydro-2H-1-benzopyran-4-imine → 6-Chloro-7-methyl-3,4-dihydro-2H-1-benzopyran-4-amine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (4E)-N-Methoxy-6-methyl-3,4-dihydro-2H-1-benzopyran-4-imine | HCID 86605441 | — |
| Reactant | 6-Chloro-7-methylchroman-4-one O-methyl oxime | HCID 86605442 | — |
| Product | 6-Chloro-7-methyl-3,4-dihydro-2H-1-benzopyran-4-amine | HCID 16643029 | — |
Reaction Steps
The title compound was prepared using the procedure as described in Example 7B, substituting the product of Example 13A for the product of Example 7A. 1H NMR (300 MHz, CDCl3) δ 7.27 (s, 1H), 6.68 (s, 1H), 4.15-4.29 (m, 2H), 3.98 (m, 1H), 2.29 (s, 3H), 2.07-2.17 (m, 1H), 1.75-1.85 (m, 1H). MS (DCI) m/e 198 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08440691B2 |
| Source dataset | uspto-grants-2013_05 |
| ORD ID | ord-574dfd4cd4ae4ec1a803ecf98ba1633d |
| Source note | uspto-grants-2013_05 |