HuagongsheHuagongshe Chemistry Print Report · For research reference only
Butanal → N-(1,1-Dimethylethyl)-1-butanamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Butanal | HCID 261 | — |
| Reactant | Propanal | HCID 527 | — |
| Reactant | Tert-Butylamine | HCID 6385 | — |
| Product | N-(1,1-Dimethylethyl)-1-butanamine | HCID 85447 | — |
| Product | N-tert-Butylpropan-1-amine | HCID 12426736 | — |
Reaction Steps
In an analogous manner to that in example 1c, 1.5 mol of tert-butylamine were reacted with n-propionaldehyde (example 2a) or n-butyraldehyde (example 2b) to give the corresponding secondary amines (tert-butylpropylamine and n-butyl-tert-butylamine respectively), and they were then analyzed by gas chromatography. For these reactions too, yields of 93.6 area % (example 2a) and 95.7 area % (example 2b) of the corresponding secondary amines were achieved.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08445726B2 |
| Source dataset | uspto-grants-2013_05 |
| ORD ID | ord-cebcb9426a6d459d8f49594b889d8403 |
| Source note | uspto-grants-2013_05 |