Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Triethylamine hydrochloride | HCID 11130 | — |
| Reactant | Phosphorus oxychloride | HCID 24813 | — |
| Reactant | 1-Undecanol, 2-heptyl- | HCID 95338 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 18366345 | HCID 18366345 | 34.7% |
Reaction Steps
With nitrogen substitution, 540 ml of toluene and 138.0 grams (0.9 moles) of phosphorus oxychloride were added and cooled to −10 degrees C. To this mixture, a solution of 243.5 grams (0.9 moles; 1.0 in molar ratio) of 2-heptylundecanol and 91.1 grams (0.9 moles) of triethylamine was dripped, and the mixture was reacted for 12 hours at 0 degrees C. The mixture was then heated to 25 degrees C., and a triethylamine hydrochloride was. removed by filtering to obtain 1003.9 grams of a toluene solution of (2-heptylundecyl)dichlorophosphate (34.7% in concentration).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07569211B2 |
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| Source dataset | uspto-grants-2009_08 |
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| ORD ID | ord-7f0d76c9d11240c29c8e63cfd1e166fa |
|---|
| Source note | uspto-grants-2009_08 |
|---|
