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4-Bromobenzaldehyde → 4-(5-(4-(diphenylamino)phenyl)-1-methyl-1H-pyrrol-2-yl)benzaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 4-Bromobenzaldehyde | HCID 70741 | — |
| 反応物 | 4-Bromotriphenylamine | HCID 642838 | — |
| 反応物 | 1-methyl-2-(tributylstannyl)-1H-pyrrole | HCID 2769397 | — |
| 反応物 | 4-(1-methyl-5-(tributylstannyl)-1H-pyrrole-2-yl)-N,N-diphenylaniline | HCID 57796692 | — |
| 生成物 | 4-(5-(4-(diphenylamino)phenyl)-1-methyl-1H-pyrrol-2-yl)benzaldehyde | HCID 86760928 | — |
反応手順
The compound of the present example was synthesized by the same method as described in example 1, except that 1.85 parts of 4-bromo-benzaldehyde was used to substitute 4-bromo-N,N-diphenylaniline, and 6.63 parts of 4-(1-methyl-5-(tributylstannyl)-1H-pyrrole-2-yl)-N,N-diphenylaniline (13) was used to substitute 1-methyl-2-(tributylstannyl)-1H-pyrrole, wherein 4-(1-methyl-5-(tributylstannyl)-1H-pyrrole-2-yl)-N,N-diphenylaniline (13) was synthesized according to the method illustrated in Armaroli, N.; Balzani, V. Angew. Chem. Int. Ed. 2007, 46, 52.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07569704B1 |
| 出典データセット | uspto-grants-2009_08 |
| ORD ID | ord-4b5587d14dbc4243b9bf643705ae9272 |
| 出典メモ | uspto-grants-2009_08 |