2,4-Dichlorobenzotrifluoride → Benzene, 2,4-dichloro-1-[dichloro(4-fluorophenyl)methyl]-

HRID 2103106Notes

Reaction equation

HRID 2103106 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1[C:9](F)(F)F.[Al+3].[Cl-:14].[Cl-:15].[Cl-].[F:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1>>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1[C:9]([C:21]1[CH:22]=[CH:23][C:18]([F:17])=[CH:19][CH:20]=1)([Cl:15])[Cl:14]

Participants

4

Reactant 3

HCID 94432,4-DichlorobenzotrifluorideHCID 10008FluorobenzeneHCID 6451240Aluminum(III) Chloride

Product 1

HCID 22475046Benzene, 2,4-dichloro-1-[dichloro(4-fluorophenyl)methyl]-

Procedure

From 2,4-dichlorobenzotrifluoride (215 mg, 1 mmol), AlCl3 (400 mg, 3 mmol) and fluorobenzene (96 mg, 1 mmol), light yellow oil (382 mg, 118% crude).

Sources & evidence

ORD record
ord-87f5ae26bafe4cc5bbb2483b8e02eb14
Source dataset
uspto-grants-2009_08
Patent number
US07576088B2

Reaction notes

Loading…