HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromopinacolone → 2,2-Dimethyl-1-(3-methyl-1-benzothien-2-yl)propan-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromopinacolone | HCID 21642 | — |
| Reactant | 1-(2-Sulfanylphenyl)ethan-1-one | HCID 11094819 | — |
| Product | 2,2-Dimethyl-1-(3-methyl-1-benzothien-2-yl)propan-1-one | HCID 20772321 | — |
Reaction Steps
The title compound was prepared from 1-(2-mercaptophenyl)ethanone and 1-bromopinacolone using the procedure in Step B Examples 36˜49. 1H NMR (CDCl3, 500 MHz) 7.82˜7.88 (m, 2H), 7.44˜7.50 (m, 2H), 2.60 (s, 3H), 1.41 (s, 9H). LC-MS: 4.06 min. (m/Z=233.4, 191).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07576122B2 |
| Source dataset | uspto-grants-2009_08 |
| ORD ID | ord-e499ff48e4fc4f77a90d87848303f2f6 |
| Source note | uspto-grants-2009_08 |