(3-Iodopropyl)trimethoxysilane → HCID 57804717, compound

HRID 2103959Notes

Reaction equation

HRID 2103959 reaction equation
[SH:1][C:2]1[N:7]=[CH:6][CH:5]=[CH:4][N:3]=1.I[CH2:9][CH2:10][CH2:11][Si:12]([O:17][CH3:18])([O:15][CH3:16])[O:13][CH3:14]>>[CH3:14][O:13][Si:12]([O:17][CH3:18])([O:15][CH3:16])[CH2:11][CH2:10][CH2:9][S:1][C:2]1[N:7]=[CH:6][CH:5]=[CH:4][N:3]=1

Participants

3

Reactant 2

HCID 2759373(3-Iodopropyl)trimethoxysilaneHCID 178418793HCID 178418793, compound

Product 1

HCID 57804717HCID 57804717, compoundYield 74%

Procedure

2-(3-(trimethoxysilyl)propylthio)pyrimidine was synthesized from 2-mercaptopyrimidine and iodopropyltrimethoxysilane in the similar method as described above. 1H NMR (CD3Cl): δ(ppm) 8.62 (2H, m, Pyr.-H), 7.11 (1H, m, Pyr.-H), 3.57 (9H, s, —CH3), 3.25 (2H, m, —CH2—), 1.88 (2H, m, —CH2—), 0.83 (2H, t, JH-H=8.25, —CH2—). Yield: 74%.

Sources & evidence

ORD record
ord-1edf3686f5a0435f9305616ab74d36e8
Source dataset
uspto-grants-2009_08
Patent number
US07576165B2

Reaction notes

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