HRID2104225

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：C[C@@H]1OC(=O)[C@H](OC(=O)c2ccccc2)[C@H](OC(=O)c2ccccc2)[C@H]1OC(=O)c1ccccc1

HCID11236842

未命名化合物

PRODUCTS

生成物

结构：C[C@@H]1OC(=O)C(OC(=O)c2ccccc2)=C[C@H]1OC(=O)c1ccccc1

HCID11221893

未命名化合物

收率 65%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID18929042

未命名化合物

PROCEDURE

实验过程

The compound (VII) (13.2 g, 27.8 mmol) is dissolved in Et3N:CHCl3 (1:4, 500 ml) under N2 current and stirred for 16 hours at a room temperature. After the reaction is finished, it is washed by water. An organic layer is dried using anhydrous MgSO4. The solution is vacuum concentrated and then the compound (VIII) (6.37 g, 65%) is isolated using flash column chromatography (toluene/EtOAc, 10:1, v/v).

WORKUP

后处理

washit is washed by water
customAn organic layer is dried
concentrationconcentrated