HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → 3-(1-ethoxycarbonylpentoxy)-1-phenyl-1,2,4-1H-triazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Ethyl 2-bromohexanoate | HCID 79072 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | HCID 178517978 | HCID 178517978 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | 3-(1-ethoxycarbonylpentoxy)-1-phenyl-1,2,4-1H-triazole | HCID 15016252 | 27.7% |
Reaction Steps
The process was carried out as shown in Example 7 above, beginning with 1.4 g of sodium, 30 ml of methanol, 150 ml of dimethylsulfoxide, 10 g of 3-hydroxy-1-phenyl-1,2,4-1H-triazole and 13.8 g of ethyl 2-bromohexanoate. The product was distilled at 205° and 1 mm of mercury to obtain 5.2 g of the desired product, an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04931083 |
| Source dataset | uspto-grants-1990_06 |
| ORD ID | ord-ead8a7bf3c5447a3a02cd77f33518811 |
| Source note | uspto-grants-1990_06 |