Potassium Hydroxide → HCID 15016264, compound

HRID 2106587Notes

Reaction equation

HRID 2106587 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[N:8]1[CH:12]=[N:11][C:10]([O:13][CH:14]([C:16]([O:18]CC)=[O:17])[CH3:15])=[N:9]1.[OH-].[K+]>C(O)C>[C:16]([CH:14]([O:13][C:10]1[N:11]=[CH:12][N:8]([C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=2[Cl:1])[N:9]=1)[CH3:15])([OH:18])=[O:17]

Participants

4

Reactant 2

HCID 14797Potassium HydroxideHCID 14268788HCID 14268788, compound

Product 1

HCID 15016264HCID 15016264, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Ten g of the compound of Example 4 was refluxed for 4 hours with 3.8 g of potassium hydroxide in 100 ml of ethanol, and the product was collected as shown in Example 22 and recrystallized from toluene and then from ethanol to obtain 3.1 g of the desired product, m.p. 104°-106°.

Workup

  1. customthe product was collected
  2. customrecrystallized from toluene

Sources & evidence

ORD record
ord-d26ad51924ae4c1ebb41c70af358abc2
Source dataset
uspto-grants-1990_06
Patent number
US04931083

Reaction notes

Loading…