HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → 1-(1-Ethoxyethylidene)-2-(4-nitrophenyl)hydrazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Ethanimidic acid, ethyl ester, hydrochloride (1:1) | HCID 2724290 | — |
| Reactant | (4-Nitrophenyl)hydrazine | HCID 3310889 | — |
| Solvent | Water | HCID 962 | — |
| Product | 1-(1-Ethoxyethylidene)-2-(4-nitrophenyl)hydrazine | HCID 53940589 | 85% |
Reaction Steps
To a stirred and cooled (ice-bath) mixture of 15 parts of 1-(4-nitrophenyl)hydrazine and 160 parts of absolute ethanol were added 13.5 parts of ethyl ethanimidate hydrochloride. After stirring for 3 hours while cooling, the reaction mixture was poured into water. The precipitated product was filtered off, washed with water and dried, yielding 19 parts (85%) of 1-(1-ethoxyethylidene)-2-(4-nitrophenyl)hydrazine; mp. 101.8° C. (int. 18).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04931444 |
| Source dataset | uspto-grants-1990_06 |
| ORD ID | ord-93c3f25e38054d6ab7bc7d31da175792 |
| Source note | uspto-grants-1990_06 |