Ammonia → HCID 53965123, compound

HRID 2107209Notes

Reaction equation

HRID 2107209 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([NH:9][C:10]2[S:11][CH:12]=[C:13]([CH:15]=O)[N:14]=2)=[CH:5][CH:4]=1.[S:17]1[CH2:23][C:21](=[O:22])[N:20]([CH2:24][C:25]([OH:27])=[O:26])[C:18]1=[S:19].[Cl-].[NH4+].N>C(O)C>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]([NH:9][C:10]2[S:11][CH:12]=[C:13]([CH:15]=[C:23]3[S:17][C:18](=[S:19])[N:20]([CH2:24][C:25]([OH:27])=[O:26])[C:21]3=[O:22])[N:14]=2)=[CH:7][CH:8]=1

Participants

6

Reactant 4

HCID 222AmmoniaHCID 25517Ammonium ChlorideHCID 797933-Thiazolidineacetic acid, 4-oxo-2-thioxo-HCID 15053573HCID 15053573, compound

Product 1

HCID 53965123HCID 53965123, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The reaction described in Example 1 was repeated, but using 1 g of 2-(p-anisidino)thiazole-4-carbaldehyde, 0.8 g of rhodanine-3-acetic acid 0.5 g of ammonium chloride, 0.5 ml of 28% v/v aqueous ammonia, and 10 ml of ethanol, giving the title compound as an orange powder.

Sources & evidence

ORD record
ord-cd94be50471b47b48fc02612457733f1
Source dataset
uspto-grants-1990_06
Patent number
US04933355

Reaction notes

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