Ammonia → HCID 54343055, compound

HRID 2107214Notes

Reaction equation

HRID 2107214 reaction equation
[C:1]1([N:7]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[C:8]2[S:9][CH:10]=[C:11]([CH:13]=O)[N:12]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[S:21]1[CH2:27][C:25](=[O:26])[N:24]([CH2:28][C:29]([OH:31])=[O:30])[C:22]1=[S:23].[Cl-].[NH4+].N>C(O)C>[C:1]1([N:7]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[C:8]2[S:9][CH:10]=[C:11]([CH:13]=[C:27]3[S:21][C:22](=[S:23])[N:24]([CH2:28][C:29]([OH:31])=[O:30])[C:25]3=[O:26])[N:12]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

6

Reactant 4

HCID 222AmmoniaHCID 25517Ammonium ChlorideHCID 797933-Thiazolidineacetic acid, 4-oxo-2-thioxo-HCID 150535782-Diphenylaminothiazole-4-carbaldehyde

Product 1

HCID 54343055HCID 54343055, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The reaction described in Example 1 was repeated, but using 3 g of 2-diphenylaminothiazole-4-carbaldehyde, 1.7 g of rhodanine-3-acetic acid, 1.3 g of ammonium chloride, 1.3 ml of 28% v/v aqueous ammonia and 60 ml of ethanol, giving the title compound as orange needles.

Sources & evidence

ORD record
ord-96ae2a1da2a3467cad28722d8772b0a9
Source dataset
uspto-grants-1990_06
Patent number
US04933355

Reaction notes

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