Ethyl bromopyruvate → 126534-13-2

HRID 2107304Notes

Reaction equation

HRID 2107304 reaction equation
[CH2:1]([NH:8][C:9]([NH2:11])=[S:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[CH2:13][C:14](=O)[C:15]([O:17][CH2:18][CH3:19])=[O:16]>C(O)C>[CH2:1]([NH:8][C:9]1[S:10][CH:13]=[C:14]([C:15]([O:17][CH2:18][CH3:19])=[O:16])[N:11]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 66144Ethyl bromopyruvateHCID 737375N-(Phenylmethyl)thiourea

Product 1

HCID 15053550126534-13-2

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The reaction described in Preparation 42 was repeated, but using 5.02 g of benzylthiourea, 5.87 g of ethyl bromopyruvate and 50 ml of ethanol, giving the title compound as pale yellow needles.

Workup

  1. customThe reaction described in Preparation 42

Sources & evidence

ORD record
ord-c642e0eb7a694eb09834017caac17d1c
Source dataset
uspto-grants-1990_06
Patent number
US04933355

Reaction notes

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